Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
Resumen:
This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites.
| 2025 | |
| Agencia Nacional de Investigación e Innovación | |
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Oil shale Smouldering combustion Waste to energy Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica Ingeniería y Tecnología Ingeniería Química Ingeniería del Medio Ambiente Ingeniería del Petróleo, Energía y Combustibles |
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| Inglés | |
| Agencia Nacional de Investigación e Innovación | |
| REDI | |
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https://hdl.handle.net/20.500.12381/5327
https://doi.org/10.1016/j.fuel.2025.136546 |
|
| Acceso embargado | |
| Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND) |
| _version_ | 1875749912837095424 |
|---|---|
| author | Torres Brunengo, Martin Miguel |
| author2 | Wyn, Hons K. Cuña, Andrés Faccio, Ricardo Castiglioni, Jorge Yermán, Luis |
| author2_role | author author author author author |
| author_facet | Torres Brunengo, Martin Miguel Wyn, Hons K. Cuña, Andrés Faccio, Ricardo Castiglioni, Jorge Yermán, Luis |
| author_role | author |
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| collection | REDI |
| dc.creator.none.fl_str_mv | Torres Brunengo, Martin Miguel Wyn, Hons K. Cuña, Andrés Faccio, Ricardo Castiglioni, Jorge Yermán, Luis |
| dc.date.accessioned.none.fl_str_mv | 2025-12-10T13:15:18Z |
| dc.date.issued.none.fl_str_mv | 2025-08-18 |
| dc.description.abstract.none.fl_txt_mv | This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites. |
| dc.description.sponsorship.none.fl_txt_mv | Agencia Nacional de Investigación e Innovación |
| dc.identifier.anii.es.fl_str_mv | FCE_3_2020_1_161919 |
| dc.identifier.doi.none.fl_str_mv | https://doi.org/10.1016/j.fuel.2025.136546 |
| dc.identifier.uri.none.fl_str_mv | https://hdl.handle.net/20.500.12381/5327 |
| dc.language.iso.none.fl_str_mv | eng |
| dc.publisher.es.fl_str_mv | Elsevier |
| dc.relation.none.fl_str_mv | https://hdl.handle.net/20.500.12381/3410 https://hdl.handle.net/20.500.12381/3407 https://hdl.handle.net/20.500.12381/3408 https://hdl.handle.net/20.500.12381/3409 https://hdl.handle.net/20.500.12381/3584 |
| dc.rights.*.fl_str_mv | Acceso embargado |
| dc.rights.embargoend.*.fl_str_mv | 2027-08-18 |
| dc.rights.embargoreason.*.fl_str_mv | Embargo por politicas de la revista |
| dc.rights.embargoterm.*.fl_str_mv | 2027-08-18 |
| dc.rights.license.none.fl_str_mv | Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND) |
| dc.rights.none.fl_str_mv | info:eu-repo/semantics/embargoedAccess |
| dc.source.es.fl_str_mv | Fuel |
| dc.source.none.fl_str_mv | reponame:REDI instname:Agencia Nacional de Investigación e Innovación instacron:Agencia Nacional de Investigación e Innovación |
| dc.subject.anii.none.fl_str_mv | Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica Ingeniería y Tecnología Ingeniería Química Ingeniería del Medio Ambiente Ingeniería del Petróleo, Energía y Combustibles |
| dc.subject.es.fl_str_mv | Oil shale Smouldering combustion Waste to energy |
| dc.title.none.fl_str_mv | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition |
| dc.type.es.fl_str_mv | Artículo |
| dc.type.none.fl_str_mv | info:eu-repo/semantics/article |
| dc.type.version.es.fl_str_mv | Aceptado |
| dc.type.version.none.fl_str_mv | info:eu-repo/semantics/acceptedVersion |
| description | This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites. |
| eu_rights_str_mv | embargoedAccess |
| format | article |
| id | REDI_1da74f30cdf3c7e36e1bd44fa996bcbe |
| identifier_str_mv | FCE_3_2020_1_161919 |
| instacron_str | Agencia Nacional de Investigación e Innovación |
| institution | Agencia Nacional de Investigación e Innovación |
| instname_str | Agencia Nacional de Investigación e Innovación |
| language | eng |
| network_acronym_str | REDI |
| network_name_str | REDI |
| oai_identifier_str | oai:redi.anii.org.uy:20.500.12381/5327 |
| publishDate | 2025 |
| reponame_str | REDI |
| repository.mail.fl_str_mv | jmaldini@anii.org.uy |
| repository.name.fl_str_mv | REDI - Agencia Nacional de Investigación e Innovación |
| repository_id_str | 9421 |
| rights_invalid_str_mv | Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND) Acceso embargado 2027-08-18 Embargo por politicas de la revista |
| spelling | Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND)Acceso embargado2027-08-18Embargo por politicas de la revista2027-08-18info:eu-repo/semantics/embargoedAccess2025-12-10T13:15:18Z2025-08-18https://hdl.handle.net/20.500.12381/5327FCE_3_2020_1_161919https://doi.org/10.1016/j.fuel.2025.136546This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites.Agencia Nacional de Investigación e InnovaciónengElsevierhttps://hdl.handle.net/20.500.12381/3410https://hdl.handle.net/20.500.12381/3407https://hdl.handle.net/20.500.12381/3408https://hdl.handle.net/20.500.12381/3409https://hdl.handle.net/20.500.12381/3584Fuelreponame:REDIinstname:Agencia Nacional de Investigación e Innovacióninstacron:Agencia Nacional de Investigación e InnovaciónOil shaleSmouldering combustionWaste to energyCiencias Naturales y ExactasCiencias QuímicasFísico-Química, Ciencia de los Polímeros, ElectroquímicaIngeniería y TecnologíaIngeniería QuímicaIngeniería del Medio AmbienteIngeniería del Petróleo, Energía y CombustiblesSelf-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass additionArtículoAceptadoinfo:eu-repo/semantics/acceptedVersioninfo:eu-repo/semantics/articleUniversidad de la República. Facultad de QuímicaThe University of Queensland//Ciencias Naturales y Exactas/Ciencias Químicas/Físico-Química, Ciencia de los Polímeros, Electroquímica//Ingeniería y Tecnología/Ingeniería Química/Ingeniería Química//Ingeniería y Tecnología/Ingeniería del Medio Ambiente/Ingeniería del Petróleo, Energía y CombustiblesTorres Brunengo, Martin MiguelWyn, Hons K.Cuña, AndrésFaccio, RicardoCastiglioni, JorgeYermán, LuisLICENSElicense.txtlicense.txttext/plain; charset=utf-84967https://redi.anii.org.uy/jspui/bitstream/20.500.12381/5327/3/license.txta4ce09f01b5dd771727aa05c73851623MD53ORIGINALManuscript OS.pdfManuscript OS.pdfManuscritoapplication/pdf1580665https://redi.anii.org.uy/jspui/bitstream/20.500.12381/5327/1/Manuscript%20OS.pdf7ceda476cdcf5bb5faecb74ff86e63d3MD51Supplementary material.pdfSupplementary material.pdfMaterial Suplementarioapplication/pdf994708https://redi.anii.org.uy/jspui/bitstream/20.500.12381/5327/2/Supplementary%20material.pdf1d4ff739a8ac0d52734b5da8d794f801MD5220.500.12381/53272026-02-09 14:00:06.506oai:redi.anii.org.uy:20.500.12381/5327Institucionalhttps://redi.anii.org.uy/Gobiernohttps://www.anii.org.uy/https://redi.anii.org.uy/oai/requestjmaldini@anii.org.uyUruguayopendoar:94212026-02-09T17:00:06REDI - Agencia Nacional de Investigación e Innovaciónfalse |
| spellingShingle | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition Torres Brunengo, Martin Miguel Oil shale Smouldering combustion Waste to energy Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica Ingeniería y Tecnología Ingeniería Química Ingeniería del Medio Ambiente Ingeniería del Petróleo, Energía y Combustibles |
| status_str | acceptedVersion |
| title | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition |
| title_full | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition |
| title_fullStr | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition |
| title_full_unstemmed | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition |
| title_short | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition |
| title_sort | Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition |
| topic | Oil shale Smouldering combustion Waste to energy Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica Ingeniería y Tecnología Ingeniería Química Ingeniería del Medio Ambiente Ingeniería del Petróleo, Energía y Combustibles |
| url | https://hdl.handle.net/20.500.12381/5327 https://doi.org/10.1016/j.fuel.2025.136546 |