Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition

Torres Brunengo, Martin Miguel - Wyn, Hons K. - Cuña, Andrés - Faccio, Ricardo - Castiglioni, Jorge - Yermán, Luis

Resumen:

This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites.

Detalles Bibliográficos
2025
Agencia Nacional de Investigación e Innovación
Oil shale
Smouldering combustion
Waste to energy
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
Ingeniería y Tecnología
Ingeniería Química
Ingeniería del Medio Ambiente
Ingeniería del Petróleo, Energía y Combustibles
Inglés
Agencia Nacional de Investigación e Innovación
REDI
https://hdl.handle.net/20.500.12381/5327
https://doi.org/10.1016/j.fuel.2025.136546
Acceso embargado
Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND)
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author Torres Brunengo, Martin Miguel
author2 Wyn, Hons K.
Cuña, Andrés
Faccio, Ricardo
Castiglioni, Jorge
Yermán, Luis
author2_role author
author
author
author
author
author_facet Torres Brunengo, Martin Miguel
Wyn, Hons K.
Cuña, Andrés
Faccio, Ricardo
Castiglioni, Jorge
Yermán, Luis
author_role author
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https://redi.anii.org.uy/jspui/bitstream/20.500.12381/5327/2/Supplementary%20material.pdf
collection REDI
dc.creator.none.fl_str_mv Torres Brunengo, Martin Miguel
Wyn, Hons K.
Cuña, Andrés
Faccio, Ricardo
Castiglioni, Jorge
Yermán, Luis
dc.date.accessioned.none.fl_str_mv 2025-12-10T13:15:18Z
dc.date.issued.none.fl_str_mv 2025-08-18
dc.description.abstract.none.fl_txt_mv This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites.
dc.description.sponsorship.none.fl_txt_mv Agencia Nacional de Investigación e Innovación
dc.identifier.anii.es.fl_str_mv FCE_3_2020_1_161919
dc.identifier.doi.none.fl_str_mv https://doi.org/10.1016/j.fuel.2025.136546
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12381/5327
dc.language.iso.none.fl_str_mv eng
dc.publisher.es.fl_str_mv Elsevier
dc.relation.none.fl_str_mv https://hdl.handle.net/20.500.12381/3410
https://hdl.handle.net/20.500.12381/3407
https://hdl.handle.net/20.500.12381/3408
https://hdl.handle.net/20.500.12381/3409
https://hdl.handle.net/20.500.12381/3584
dc.rights.*.fl_str_mv Acceso embargado
dc.rights.embargoend.*.fl_str_mv 2027-08-18
dc.rights.embargoreason.*.fl_str_mv Embargo por politicas de la revista
dc.rights.embargoterm.*.fl_str_mv 2027-08-18
dc.rights.license.none.fl_str_mv Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND)
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
dc.source.es.fl_str_mv Fuel
dc.source.none.fl_str_mv reponame:REDI
instname:Agencia Nacional de Investigación e Innovación
instacron:Agencia Nacional de Investigación e Innovación
dc.subject.anii.none.fl_str_mv Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
Ingeniería y Tecnología
Ingeniería Química
Ingeniería del Medio Ambiente
Ingeniería del Petróleo, Energía y Combustibles
dc.subject.es.fl_str_mv Oil shale
Smouldering combustion
Waste to energy
dc.title.none.fl_str_mv Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
dc.type.es.fl_str_mv Artículo
dc.type.none.fl_str_mv info:eu-repo/semantics/article
dc.type.version.es.fl_str_mv Aceptado
dc.type.version.none.fl_str_mv info:eu-repo/semantics/acceptedVersion
description This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites.
eu_rights_str_mv embargoedAccess
format article
id REDI_1da74f30cdf3c7e36e1bd44fa996bcbe
identifier_str_mv FCE_3_2020_1_161919
instacron_str Agencia Nacional de Investigación e Innovación
institution Agencia Nacional de Investigación e Innovación
instname_str Agencia Nacional de Investigación e Innovación
language eng
network_acronym_str REDI
network_name_str REDI
oai_identifier_str oai:redi.anii.org.uy:20.500.12381/5327
publishDate 2025
reponame_str REDI
repository.mail.fl_str_mv jmaldini@anii.org.uy
repository.name.fl_str_mv REDI - Agencia Nacional de Investigación e Innovación
repository_id_str 9421
rights_invalid_str_mv Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND)
Acceso embargado
2027-08-18
Embargo por politicas de la revista
spelling Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional. (CC BY-NC-ND)Acceso embargado2027-08-18Embargo por politicas de la revista2027-08-18info:eu-repo/semantics/embargoedAccess2025-12-10T13:15:18Z2025-08-18https://hdl.handle.net/20.500.12381/5327FCE_3_2020_1_161919https://doi.org/10.1016/j.fuel.2025.136546This work presents a proof of concept for the application of smouldering combustion to valorize Uruguayan oil shales as a solid fuel resource. Due to their low calorific value oil shales mixed with biomass waste were tested under controlled conditions to assess their suitability for energy recovery. Experiments were conducted in a fixed-bed reactor to investigate the influence of air Darcy flux and particle size on the smouldering gas composition and its calorific value. Results show that a minimum air Darcy flux of 3 cm/s is required for self-sustained smouldering when using oil shales particles with 1.2–1.6 mm in size. The addition of 50 wt.% of biomass waste, as a supplementary fuel, increased the gas calorific value from 3.0 to 4.4 MJ/Nm3. The net energy balance analysis showed a shift from negative to positive net energy gain with increasing biomass, reaching up to 25% relative to the energy required for aeration in the scale tested. Analysis by X-ray diffraction and fluorescence of the residual ash identified crystalline phases and metals, indicating potential for valorisation due to presence of Fe, quartz, muscovite and zeolites.Agencia Nacional de Investigación e InnovaciónengElsevierhttps://hdl.handle.net/20.500.12381/3410https://hdl.handle.net/20.500.12381/3407https://hdl.handle.net/20.500.12381/3408https://hdl.handle.net/20.500.12381/3409https://hdl.handle.net/20.500.12381/3584Fuelreponame:REDIinstname:Agencia Nacional de Investigación e Innovacióninstacron:Agencia Nacional de Investigación e InnovaciónOil shaleSmouldering combustionWaste to energyCiencias Naturales y ExactasCiencias QuímicasFísico-Química, Ciencia de los Polímeros, ElectroquímicaIngeniería y TecnologíaIngeniería QuímicaIngeniería del Medio AmbienteIngeniería del Petróleo, Energía y CombustiblesSelf-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass additionArtículoAceptadoinfo:eu-repo/semantics/acceptedVersioninfo:eu-repo/semantics/articleUniversidad de la República. Facultad de QuímicaThe University of Queensland//Ciencias Naturales y Exactas/Ciencias Químicas/Físico-Química, Ciencia de los Polímeros, Electroquímica//Ingeniería y Tecnología/Ingeniería Química/Ingeniería Química//Ingeniería y Tecnología/Ingeniería del Medio Ambiente/Ingeniería del Petróleo, Energía y CombustiblesTorres Brunengo, Martin MiguelWyn, Hons K.Cuña, AndrésFaccio, RicardoCastiglioni, JorgeYermán, LuisLICENSElicense.txtlicense.txttext/plain; charset=utf-84967https://redi.anii.org.uy/jspui/bitstream/20.500.12381/5327/3/license.txta4ce09f01b5dd771727aa05c73851623MD53ORIGINALManuscript OS.pdfManuscript OS.pdfManuscritoapplication/pdf1580665https://redi.anii.org.uy/jspui/bitstream/20.500.12381/5327/1/Manuscript%20OS.pdf7ceda476cdcf5bb5faecb74ff86e63d3MD51Supplementary material.pdfSupplementary material.pdfMaterial Suplementarioapplication/pdf994708https://redi.anii.org.uy/jspui/bitstream/20.500.12381/5327/2/Supplementary%20material.pdf1d4ff739a8ac0d52734b5da8d794f801MD5220.500.12381/53272026-02-09 14:00:06.506oai:redi.anii.org.uy:20.500.12381/5327Institucionalhttps://redi.anii.org.uy/Gobiernohttps://www.anii.org.uy/https://redi.anii.org.uy/oai/requestjmaldini@anii.org.uyUruguayopendoar:94212026-02-09T17:00:06REDI - Agencia Nacional de Investigación e Innovaciónfalse
spellingShingle Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
Torres Brunengo, Martin Miguel
Oil shale
Smouldering combustion
Waste to energy
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
Ingeniería y Tecnología
Ingeniería Química
Ingeniería del Medio Ambiente
Ingeniería del Petróleo, Energía y Combustibles
status_str acceptedVersion
title Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
title_full Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
title_fullStr Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
title_full_unstemmed Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
title_short Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
title_sort Self-sustained smouldering of low-calorific Uruguayan oil shales: influence of operational parameters and biomass addition
topic Oil shale
Smouldering combustion
Waste to energy
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
Ingeniería y Tecnología
Ingeniería Química
Ingeniería del Medio Ambiente
Ingeniería del Petróleo, Energía y Combustibles
url https://hdl.handle.net/20.500.12381/5327
https://doi.org/10.1016/j.fuel.2025.136546