Catalytic hydrophosphorylation of propiolates and three-component phosphorylation of aldehydes

Delgado-Hernández, Samuel - Peixoto de Abreu Lima, Alejandro - Martín-Díaz, Eva M. - Scoccia, Jimena - Carrillo, Romen - Tejedor, David

Resumen:

A practical and efficient regio- and stereoselective hydrophosphorylation of propiolates, as well as a multicomponent reaction incorporating an aldehyde component, is reported. Both processes proceed with atom economy in very straightforward experimental procedures. The reactions are catalyzed by DABCO (1,4- diazabicyclo[2.2.2]octane) and use readily available H-phosphonates as the phosphorylating agent.

Detalles Bibliográficos
2026
Aldehídos
Alquilos
Catalizadores
Hidrocarburos
Compuestos organofosforados
Inglés
Universidad de la República
COLIBRI
https://hdl.handle.net/20.500.12008/55398
Acceso abierto
Licencia Creative Commons Atribución (CC - By 4.0)