Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs
Resumen:
The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6] 12H2O}n of mixed hexagonal/decagonal (63 103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition togive the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6] 4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n.
| 2024 | |
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OXALATO HOLMIO EFECTO MAGNETOCALORICO |
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| Inglés | |
| Universidad de la República | |
| COLIBRI | |
| https://hdl.handle.net/20.500.12008/47245 | |
| Acceso abierto | |
| Licencia Creative Commons Atribución - No Comercial (CC - By-NC 4.0) |
