Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs

El Alouani Dahmouni, Nadia - Orts-Arroyo, Marta - Sanchis-Perucho, Adrián - Moliner, Nicolás - Mayans, Júlia - Pacheco, Mario - Castro, Isabel - De Munno, Giovanni - Marino, Nadia - Ruiz-García, Rafael - Martínez-Lillo, José

Resumen:

The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6] 12H2O}n of mixed hexagonal/decagonal (63 103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition togive the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6] 4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n.

Detalles Bibliográficos
2024
OXALATO
HOLMIO
EFECTO MAGNETOCALORICO
Inglés
Universidad de la República
COLIBRI
https://hdl.handle.net/20.500.12008/47245
Acceso abierto
Licencia Creative Commons Atribución - No Comercial (CC - By-NC 4.0)

Internet

https://hdl.handle.net/20.500.12008/47245

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