Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs
Resumen:
The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6] 12H2O}n of mixed hexagonal/decagonal (63 103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition togive the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6] 4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n.
| 2024 | |
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OXALATO HOLMIO EFECTO MAGNETOCALORICO |
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| Inglés | |
| Universidad de la República | |
| COLIBRI | |
| https://hdl.handle.net/20.500.12008/47245 | |
| Acceso abierto | |
| Licencia Creative Commons Atribución - No Comercial (CC - By-NC 4.0) |
| _version_ | 1875693327125315584 |
|---|---|
| author | El Alouani Dahmouni, Nadia |
| author2 | Orts-Arroyo, Marta Sanchis-Perucho, Adrián Moliner, Nicolás Mayans, Júlia Pacheco, Mario Castro, Isabel De Munno, Giovanni Marino, Nadia Ruiz-García, Rafael Martínez-Lillo, José |
| author2_role | author author author author author author author author author author |
| author_facet | El Alouani Dahmouni, Nadia Orts-Arroyo, Marta Sanchis-Perucho, Adrián Moliner, Nicolás Mayans, Júlia Pacheco, Mario Castro, Isabel De Munno, Giovanni Marino, Nadia Ruiz-García, Rafael Martínez-Lillo, José |
| author_role | author |
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| collection | COLIBRI |
| dc.contributor.filiacion.none.fl_str_mv | El Alouani Dahmouni Nadia, Universitat de València (España). Instituto de Ciencia Molecular (ICMol) Orts-Arroyo Marta, Università della Calabria (Italia). Dipartimento di Chimica. Centro di Eccellenza CEMIF.CAL Sanchis-Perucho Adrián, Universitat de València (España). Instituto de Ciencia Molecular (ICMol) Moliner Nicolás, Universitat de València (España). Instituto de Ciencia Molecular (ICMol) Mayans Júlia, Universitat de València (España). Instituto de Ciencia Molecular (ICMol) Pacheco Mario, Universitat de València (España). Instituto de Ciencia Molecular (ICMol); Universidad de la República (Uruguay). Facultad de Química. Castro Isabel, Universitat de València (España). Instituto de Ciencia Molecular (ICMol) De Munno Giovanni, Università della Calabria (Italia). Dipartimento di Chimica. Centro di Eccellenza CEMIF.CAL Marino Nadia, Università della Calabria (Italia). Dipartimento di Chimica. Centro di Eccellenza CEMIF.CAL Ruiz-García Rafael, Universitat de València (España). Instituto de Ciencia Molecular (ICMol) Martínez-Lillo José, Universitat de València (España). Instituto de Ciencia Molecular (ICMol) |
| dc.creator.none.fl_str_mv | El Alouani Dahmouni, Nadia Orts-Arroyo, Marta Sanchis-Perucho, Adrián Moliner, Nicolás Mayans, Júlia Pacheco, Mario Castro, Isabel De Munno, Giovanni Marino, Nadia Ruiz-García, Rafael Martínez-Lillo, José |
| dc.date.accessioned.none.fl_str_mv | 2024-11-28T15:00:22Z |
| dc.date.available.none.fl_str_mv | 2024-11-28T15:00:22Z |
| dc.date.issued.none.fl_str_mv | 2024 |
| dc.description.abstract.none.fl_txt_mv | The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6] 12H2O}n of mixed hexagonal/decagonal (63 103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition togive the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6] 4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n. |
| dc.format.extent.es.fl_str_mv | 4 p. |
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| dc.identifier.citation.es.fl_str_mv | El Alouani Dahmouni, N, Orts-Arroyo, M, Sanchis-Perucho, A, y otros. "Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs". Chemical Communications. [en línea] v. 60, nº 58, 2024 -- pp. 7451-7454 .DOI:10.1039/d4cc02539c |
| dc.identifier.doi.none.fl_str_mv | 10.1039/d4cc02539c |
| dc.identifier.uri.none.fl_str_mv | https://hdl.handle.net/20.500.12008/47245 |
| dc.language.iso.none.fl_str_mv | en eng |
| dc.publisher.es.fl_str_mv | Royal Society of Chemistry |
| dc.relation.none.fl_str_mv | Chemical Communications, v. 60, nº 58, 2024 -- pp. 7451-7454 |
| dc.rights.license.none.fl_str_mv | Licencia Creative Commons Atribución - No Comercial (CC - By-NC 4.0) |
| dc.rights.none.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.source.none.fl_str_mv | reponame:COLIBRI instname:Universidad de la República instacron:Universidad de la República |
| dc.subject.other.es.fl_str_mv | OXALATO HOLMIO EFECTO MAGNETOCALORICO |
| dc.title.none.fl_str_mv | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs |
| dc.type.es.fl_str_mv | Artículo |
| dc.type.none.fl_str_mv | info:eu-repo/semantics/article |
| dc.type.version.none.fl_str_mv | info:eu-repo/semantics/publishedVersion |
| description | The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6] 12H2O}n of mixed hexagonal/decagonal (63 103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition togive the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6] 4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | COLIBRI_cd5ece4b7cc7de18b712a4e9f17592c0 |
| identifier_str_mv | El Alouani Dahmouni, N, Orts-Arroyo, M, Sanchis-Perucho, A, y otros. "Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs". Chemical Communications. [en línea] v. 60, nº 58, 2024 -- pp. 7451-7454 .DOI:10.1039/d4cc02539c 10.1039/d4cc02539c |
| instacron_str | Universidad de la República |
| institution | Universidad de la República |
| instname_str | Universidad de la República |
| language | eng |
| language_invalid_str_mv | en |
| network_acronym_str | COLIBRI |
| network_name_str | COLIBRI |
| oai_identifier_str | oai:colibri.udelar.edu.uy:20.500.12008/47245 |
| publishDate | 2024 |
| reponame_str | COLIBRI |
| repository.mail.fl_str_mv | karina.camps@seciu.edu.uy |
| repository.name.fl_str_mv | COLIBRI - Universidad de la República |
| repository_id_str | 4771 |
| rights_invalid_str_mv | Licencia Creative Commons Atribución - No Comercial (CC - By-NC 4.0) |
| spelling | El Alouani Dahmouni Nadia, Universitat de València (España). Instituto de Ciencia Molecular (ICMol)Orts-Arroyo Marta, Università della Calabria (Italia). Dipartimento di Chimica. Centro di Eccellenza CEMIF.CALSanchis-Perucho Adrián, Universitat de València (España). Instituto de Ciencia Molecular (ICMol)Moliner Nicolás, Universitat de València (España). Instituto de Ciencia Molecular (ICMol)Mayans Júlia, Universitat de València (España). Instituto de Ciencia Molecular (ICMol)Pacheco Mario, Universitat de València (España). Instituto de Ciencia Molecular (ICMol); Universidad de la República (Uruguay). Facultad de Química.Castro Isabel, Universitat de València (España). Instituto de Ciencia Molecular (ICMol)De Munno Giovanni, Università della Calabria (Italia). Dipartimento di Chimica. Centro di Eccellenza CEMIF.CALMarino Nadia, Università della Calabria (Italia). Dipartimento di Chimica. Centro di Eccellenza CEMIF.CALRuiz-García Rafael, Universitat de València (España). Instituto de Ciencia Molecular (ICMol)Martínez-Lillo José, Universitat de València (España). Instituto de Ciencia Molecular (ICMol)2024-11-28T15:00:22Z2024-11-28T15:00:22Z2024El Alouani Dahmouni, N, Orts-Arroyo, M, Sanchis-Perucho, A, y otros. "Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs". Chemical Communications. [en línea] v. 60, nº 58, 2024 -- pp. 7451-7454 .DOI:10.1039/d4cc02539chttps://hdl.handle.net/20.500.12008/4724510.1039/d4cc02539cThe neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6] 12H2O}n of mixed hexagonal/decagonal (63 103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition togive the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6] 4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n.Submitted by Suhr Deborah (dsuhr@fq.edu.uy) on 2024-11-26T18:55:10Z No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 13adb202270a5f7cee03e795b33133c4 (MD5) Magnetocaloric efficiency tuning through.pdf: 591126 bytes, checksum: f67cf68690692b45de43880b74d5b943 (MD5)Rejected by Camps Karina (kcamps@psico.edu.uy), reason: Deborah, tenemos que pedirles que vuelvan a cargar la licencia CC debido a que asignaron una más restrictiva que la que posee el artículo. Deben asignarle la licencia BY-NC. Nosotras desde SeCIU no podemos cambiar la licencia. Aguardo el nuevo envío. Saludos. Karina on 2024-11-26T21:16:24Z (GMT)Submitted by Suhr Deborah (dsuhr@fq.edu.uy) on 2024-11-27T17:07:46Z No. of bitstreams: 2 license_rdf: 25207 bytes, checksum: 6e82ce373602404a137b8ed33897ec46 (MD5) Magnetocaloric efficiency tuning through.pdf: 591126 bytes, checksum: f67cf68690692b45de43880b74d5b943 (MD5)Made available in DSpace by Luna Fabiana (fabiana.luna@seciu.edu.uy) on 2024-11-28T15:00:22Z (GMT). No. of bitstreams: 2 license_rdf: 25207 bytes, checksum: 6e82ce373602404a137b8ed33897ec46 (MD5) Magnetocaloric efficiency tuning through.pdf: 591126 bytes, checksum: f67cf68690692b45de43880b74d5b943 (MD5) Previous issue date: 20244 p.application/pdfenengRoyal Society of ChemistryChemical Communications, v. 60, nº 58, 2024 -- pp. 7451-7454Las obras depositadas en el Repositorio se rigen por la Ordenanza de los Derechos de la Propiedad Intelectual de la Universidad de la República.(Res. Nº 91 de C.D.C. de 8/III/1994 – D.O. 7/IV/1994) y por la Ordenanza del Repositorio Abierto de la Universidad de la República (Res. Nº 16 de C.D.C. de 07/10/2014)info:eu-repo/semantics/openAccessLicencia Creative Commons Atribución - No Comercial (CC - By-NC 4.0)OXALATOHOLMIOEFECTO MAGNETOCALORICOMagnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFsArtículoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionreponame:COLIBRIinstname:Universidad de la Repúblicainstacron:Universidad de la RepúblicaEl Alouani Dahmouni, NadiaOrts-Arroyo, MartaSanchis-Perucho, AdriánMoliner, NicolásMayans, JúliaPacheco, MarioCastro, IsabelDe Munno, GiovanniMarino, NadiaRuiz-García, RafaelMartínez-Lillo, JoséLICENSElicense.txtlicense.txttext/plain; charset=utf-84267http://localhost:8080/xmlui/bitstream/20.500.12008/47245/5/license.txt6429389a7df7277b72b7924fdc7d47a9MD55CC-LICENSElicense_urllicense_urltext/plain; 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- Universidad de la Repúblicafalse |
| spellingShingle | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs El Alouani Dahmouni, Nadia OXALATO HOLMIO EFECTO MAGNETOCALORICO |
| status_str | publishedVersion |
| title | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs |
| title_full | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs |
| title_fullStr | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs |
| title_full_unstemmed | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs |
| title_short | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs |
| title_sort | Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs |
| topic | OXALATO HOLMIO EFECTO MAGNETOCALORICO |
| url | https://hdl.handle.net/20.500.12008/47245 |
