Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
Resumen:
Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded.
2023 | |
Agencia Nacional de Investigación e Innovación Comisión Sectorial de Investigación Científica Programa de Desarrollo de las Ciencias Básicas |
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Combustion latente autosuficiente Biomasa Energía Ingeniería y Tecnología Ingeniería Química Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica |
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Inglés | |
Agencia Nacional de Investigación e Innovación | |
REDI | |
https://hdl.handle.net/20.500.12381/3407 | |
Acceso abierto | |
Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND) |
_version_ | 1814959253389049856 |
---|---|
author | Torres Brunengo, Martín Miguel |
author2 | Yermán Martínez, Luis |
author2_role | author |
author_facet | Torres Brunengo, Martín Miguel Yermán Martínez, Luis |
author_role | author |
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bitstream.checksumAlgorithm.fl_str_mv | MD5 MD5 MD5 |
bitstream.url.fl_str_mv | https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/3/license.txt https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/1/0915%20torres%20martin%20sala%2012%20miercoles.pptx https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/2/ABSTRACT_Torres%20Brunengo_WCCE11_Smouldering.pdf |
collection | REDI |
dc.creator.none.fl_str_mv | Torres Brunengo, Martín Miguel Yermán Martínez, Luis |
dc.date.accessioned.none.fl_str_mv | 2024-01-31T13:21:52Z |
dc.date.available.none.fl_str_mv | 2024-01-31T13:21:52Z |
dc.date.issued.none.fl_str_mv | 2023-06-04 |
dc.description.abstract.none.fl_txt_mv | Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded. |
dc.description.sponsorship.none.fl_txt_mv | Agencia Nacional de Investigación e Innovación Comisión Sectorial de Investigación Científica Programa de Desarrollo de las Ciencias Básicas |
dc.identifier.anii.es.fl_str_mv | FCE_3_2020_1_161919 |
dc.identifier.uri.none.fl_str_mv | https://hdl.handle.net/20.500.12381/3407 |
dc.language.iso.none.fl_str_mv | eng |
dc.relation.uri.none.fl_str_mv | https://hdl.handle.net/20.500.12381/3408 https://hdl.handle.net/20.500.12381/3409 https://hdl.handle.net/20.500.12381/3410 |
dc.rights.*.fl_str_mv | Acceso abierto |
dc.rights.license.none.fl_str_mv | Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND) |
dc.rights.none.fl_str_mv | info:eu-repo/semantics/openAccess |
dc.source.es.fl_str_mv | 11th World Congress of Chemical Engineering. Buenos Aires, Argentina, 2023. |
dc.source.none.fl_str_mv | reponame:REDI instname:Agencia Nacional de Investigación e Innovación instacron:Agencia Nacional de Investigación e Innovación |
dc.subject.anii.none.fl_str_mv | Ingeniería y Tecnología Ingeniería Química Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica |
dc.subject.es.fl_str_mv | Combustion latente autosuficiente Biomasa Energía |
dc.title.none.fl_str_mv | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass |
dc.type.es.fl_str_mv | Documento de conferencia |
dc.type.none.fl_str_mv | info:eu-repo/semantics/conferenceObject |
dc.type.version.es.fl_str_mv | Publicado |
dc.type.version.none.fl_str_mv | info:eu-repo/semantics/publishedVersion |
description | Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded. |
eu_rights_str_mv | openAccess |
format | conferenceObject |
id | REDI_ceb4af1595da6843ecf8fc6ab60700b7 |
identifier_str_mv | FCE_3_2020_1_161919 |
instacron_str | Agencia Nacional de Investigación e Innovación |
institution | Agencia Nacional de Investigación e Innovación |
instname_str | Agencia Nacional de Investigación e Innovación |
language | eng |
network_acronym_str | REDI |
network_name_str | REDI |
oai_identifier_str | oai:redi.anii.org.uy:20.500.12381/3407 |
publishDate | 2023 |
reponame_str | REDI |
repository.mail.fl_str_mv | jmaldini@anii.org.uy |
repository.name.fl_str_mv | REDI - Agencia Nacional de Investigación e Innovación |
repository_id_str | 9421 |
rights_invalid_str_mv | Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND) Acceso abierto |
spelling | Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND)Acceso abiertoinfo:eu-repo/semantics/openAccess2024-01-31T13:21:52Z2024-01-31T13:21:52Z2023-06-04https://hdl.handle.net/20.500.12381/3407FCE_3_2020_1_161919Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded.Agencia Nacional de Investigación e InnovaciónComisión Sectorial de Investigación CientíficaPrograma de Desarrollo de las Ciencias Básicasenghttps://hdl.handle.net/20.500.12381/3408https://hdl.handle.net/20.500.12381/3409https://hdl.handle.net/20.500.12381/341011th World Congress of Chemical Engineering. Buenos Aires, Argentina, 2023.reponame:REDIinstname:Agencia Nacional de Investigación e Innovacióninstacron:Agencia Nacional de Investigación e InnovaciónCombustion latente autosuficienteBiomasaEnergíaIngeniería y TecnologíaIngeniería QuímicaCiencias Naturales y ExactasCiencias QuímicasFísico-Química, Ciencia de los Polímeros, ElectroquímicaEffect of operational parameters on the gas composition from self-sustaining smoldering of biomassDocumento de conferenciaPublicadoinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectUniversidad de la República, Facultad de Química.The University of Queensland (Australia)//Ingeniería y Tecnología/Ingeniería Química/Ingeniería Química//Ciencias Naturales y Exactas/Ciencias Químicas/Físico-Química, Ciencia de los Polímeros, ElectroquímicaTorres Brunengo, Martín MiguelYermán Martínez, LuisLICENSElicense.txtlicense.txttext/plain; charset=utf-84967https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/3/license.txta4ce09f01b5dd771727aa05c73851623MD53ORIGINAL0915 torres martin sala 12 miercoles.pptx0915 torres martin sala 12 miercoles.pptxapplication/vnd.openxmlformats-officedocument.presentationml.presentation7744621https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/1/0915%20torres%20martin%20sala%2012%20miercoles.pptxdc9e1e04c1393da2e46812b527fa6322MD51ABSTRACT_Torres Brunengo_WCCE11_Smouldering.pdfABSTRACT_Torres Brunengo_WCCE11_Smouldering.pdfapplication/pdf223639https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/2/ABSTRACT_Torres%20Brunengo_WCCE11_Smouldering.pdf88af23135e472f9d291c27a62a026996MD5220.500.12381/34072024-01-31 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- Agencia Nacional de Investigación e Innovaciónfalse |
spellingShingle | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass Torres Brunengo, Martín Miguel Combustion latente autosuficiente Biomasa Energía Ingeniería y Tecnología Ingeniería Química Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica |
status_str | publishedVersion |
title | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass |
title_full | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass |
title_fullStr | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass |
title_full_unstemmed | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass |
title_short | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass |
title_sort | Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass |
topic | Combustion latente autosuficiente Biomasa Energía Ingeniería y Tecnología Ingeniería Química Ciencias Naturales y Exactas Ciencias Químicas Físico-Química, Ciencia de los Polímeros, Electroquímica |
url | https://hdl.handle.net/20.500.12381/3407 |