Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass

Torres Brunengo, Martín Miguel - Yermán Martínez, Luis

Resumen:

Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded.


Detalles Bibliográficos
2023
Agencia Nacional de Investigación e Innovación
Comisión Sectorial de Investigación Científica
Programa de Desarrollo de las Ciencias Básicas
Combustion latente autosuficiente
Biomasa
Energía
Ingeniería y Tecnología
Ingeniería Química
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
Inglés
Agencia Nacional de Investigación e Innovación
REDI
https://hdl.handle.net/20.500.12381/3407
Acceso abierto
Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND)
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author Torres Brunengo, Martín Miguel
author2 Yermán Martínez, Luis
author2_role author
author_facet Torres Brunengo, Martín Miguel
Yermán Martínez, Luis
author_role author
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MD5
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bitstream.url.fl_str_mv https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/3/license.txt
https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/1/0915%20torres%20martin%20sala%2012%20miercoles.pptx
https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/2/ABSTRACT_Torres%20Brunengo_WCCE11_Smouldering.pdf
collection REDI
dc.creator.none.fl_str_mv Torres Brunengo, Martín Miguel
Yermán Martínez, Luis
dc.date.accessioned.none.fl_str_mv 2024-01-31T13:21:52Z
dc.date.available.none.fl_str_mv 2024-01-31T13:21:52Z
dc.date.issued.none.fl_str_mv 2023-06-04
dc.description.abstract.none.fl_txt_mv Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded.
dc.description.sponsorship.none.fl_txt_mv Agencia Nacional de Investigación e Innovación
Comisión Sectorial de Investigación Científica
Programa de Desarrollo de las Ciencias Básicas
dc.identifier.anii.es.fl_str_mv FCE_3_2020_1_161919
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12381/3407
dc.language.iso.none.fl_str_mv eng
dc.relation.uri.none.fl_str_mv https://hdl.handle.net/20.500.12381/3408
https://hdl.handle.net/20.500.12381/3409
https://hdl.handle.net/20.500.12381/3410
dc.rights.*.fl_str_mv Acceso abierto
dc.rights.license.none.fl_str_mv Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND)
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.source.es.fl_str_mv 11th World Congress of Chemical Engineering. Buenos Aires, Argentina, 2023.
dc.source.none.fl_str_mv reponame:REDI
instname:Agencia Nacional de Investigación e Innovación
instacron:Agencia Nacional de Investigación e Innovación
dc.subject.anii.none.fl_str_mv Ingeniería y Tecnología
Ingeniería Química
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
dc.subject.es.fl_str_mv Combustion latente autosuficiente
Biomasa
Energía
dc.title.none.fl_str_mv Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
dc.type.es.fl_str_mv Documento de conferencia
dc.type.none.fl_str_mv info:eu-repo/semantics/conferenceObject
dc.type.version.es.fl_str_mv Publicado
dc.type.version.none.fl_str_mv info:eu-repo/semantics/publishedVersion
description Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded.
eu_rights_str_mv openAccess
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identifier_str_mv FCE_3_2020_1_161919
instacron_str Agencia Nacional de Investigación e Innovación
institution Agencia Nacional de Investigación e Innovación
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network_name_str REDI
oai_identifier_str oai:redi.anii.org.uy:20.500.12381/3407
publishDate 2023
reponame_str REDI
repository.mail.fl_str_mv jmaldini@anii.org.uy
repository.name.fl_str_mv REDI - Agencia Nacional de Investigación e Innovación
repository_id_str 9421
rights_invalid_str_mv Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND)
Acceso abierto
spelling Reconocimiento-SinObraDerivada 4.0 Internacional. (CC BY-ND)Acceso abiertoinfo:eu-repo/semantics/openAccess2024-01-31T13:21:52Z2024-01-31T13:21:52Z2023-06-04https://hdl.handle.net/20.500.12381/3407FCE_3_2020_1_161919Smouldering is a low-temperature, flameless combustion that burns slowly. Self-sustaining smouldering (SSS) is defined as when the heat produced by exothermic oxidation with O2 overcomes the heat losses. Under adequate conditions, the process can have high energy efficiency, being self-sustaining even with solid fuels with very high moisture content (MC) (75%) without the need of additional energy. SSS combustion is a potential alternative for low-cost and on-site management of organic materials with high moisture content as well as it has been used to produce value-added products [1]. A recent work published by Serrano et. al. [2] has evaluated the application of SSS as a possible alternative for the treatment of anaerobic digestate. The authors found that SSS is suitable to accomplish nearly full digestate inertization ensuring pathogen destruction. That work evaluated the practical limits of two main operational parameters: Darcy air flux and biomass moisture content, and they found the threshold limits where SSS of digestate mixed with agricultural waste is possible. Concerning the gas composition, it has been found that this contains as the main component CO2 (60 to 70%), in addition, CO and H2 were presented in the combustion gas products in percentages around 25 and 10%, respectively. Based on these previous results, this work aims to study the sensitivity of the biomass moisture content and the air flux on the gas product composition during the smouldering of anaerobic digestate mixed with agricultural waste. Nine conditions were studied (3 MCs and 3 air Darcy flux). Gases were collected and stored in airtight glass vials and the concentrations of H2, CO2, O2, N2, CH4, and CO were measured using gas chromatography. The temperature of the reaction was measured inside the reactor at different heights and averaged. Results showed that the concentration CO and H2 increase at higher Darcy air flux and lower MCs. The highest HHV was obtained with a moisture content of 50 % and a Darcy air flux of 14.6 cm/s, resulting in the gas composition of 15, 24, 60, 1% for H2, CO, CO2, and CH4, respectively. The temperature obtained for the aforementioned experimental conditions was 960 oC, which was the highest recorded.Agencia Nacional de Investigación e InnovaciónComisión Sectorial de Investigación CientíficaPrograma de Desarrollo de las Ciencias Básicasenghttps://hdl.handle.net/20.500.12381/3408https://hdl.handle.net/20.500.12381/3409https://hdl.handle.net/20.500.12381/341011th World Congress of Chemical Engineering. Buenos Aires, Argentina, 2023.reponame:REDIinstname:Agencia Nacional de Investigación e Innovacióninstacron:Agencia Nacional de Investigación e InnovaciónCombustion latente autosuficienteBiomasaEnergíaIngeniería y TecnologíaIngeniería QuímicaCiencias Naturales y ExactasCiencias QuímicasFísico-Química, Ciencia de los Polímeros, ElectroquímicaEffect of operational parameters on the gas composition from self-sustaining smoldering of biomassDocumento de conferenciaPublicadoinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectUniversidad de la República, Facultad de Química.The University of Queensland (Australia)//Ingeniería y Tecnología/Ingeniería Química/Ingeniería Química//Ciencias Naturales y Exactas/Ciencias Químicas/Físico-Química, Ciencia de los Polímeros, ElectroquímicaTorres Brunengo, Martín MiguelYermán Martínez, LuisLICENSElicense.txtlicense.txttext/plain; charset=utf-84967https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/3/license.txta4ce09f01b5dd771727aa05c73851623MD53ORIGINAL0915 torres martin sala 12 miercoles.pptx0915 torres martin sala 12 miercoles.pptxapplication/vnd.openxmlformats-officedocument.presentationml.presentation7744621https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/1/0915%20torres%20martin%20sala%2012%20miercoles.pptxdc9e1e04c1393da2e46812b527fa6322MD51ABSTRACT_Torres Brunengo_WCCE11_Smouldering.pdfABSTRACT_Torres Brunengo_WCCE11_Smouldering.pdfapplication/pdf223639https://redi.anii.org.uy/jspui/bitstream/20.500.12381/3407/2/ABSTRACT_Torres%20Brunengo_WCCE11_Smouldering.pdf88af23135e472f9d291c27a62a026996MD5220.500.12381/34072024-01-31 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- Agencia Nacional de Investigación e Innovaciónfalse
spellingShingle Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
Torres Brunengo, Martín Miguel
Combustion latente autosuficiente
Biomasa
Energía
Ingeniería y Tecnología
Ingeniería Química
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
status_str publishedVersion
title Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
title_full Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
title_fullStr Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
title_full_unstemmed Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
title_short Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
title_sort Effect of operational parameters on the gas composition from self-sustaining smoldering of biomass
topic Combustion latente autosuficiente
Biomasa
Energía
Ingeniería y Tecnología
Ingeniería Química
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
url https://hdl.handle.net/20.500.12381/3407