Design of a AB5-metal hydride cylindrical tank for hydrogen storage

Zinola, Carlos F. - Díaz, Verónica - Teliz, Erika - Li, Yuan-lu

Resumen:

Hydrogen storage in metal hydrides presents distinct challenges which encourage the study of effective heat management strategies. Hydrogen absorption in metal hydrides is an exothermic reaction, consequently the generated heat must be removed effectively to achieve the desired performance. This work presents a mathematical model describing the adsorption of hydrogen in La Ni4.7Co0.3 metal hydride as a storage material. Heat and mass transfer effects are modeled in detail. The effect of heat transfer coefficient is also estimated. Besides, a heat transfer fluid for cooling is incorporated to the model. The problem is mathematically formulated presenting a numerical simulation of a design of a cylindrical tank for hydrogen storage. The alloy is studied by using pressure-composition-temperature curves which are carried out at different temperatures. Thermodynamic parameters and hydrogen storage capacity are determined. For isotherm's kinetics, the Jonhson-Mehl-Avrami-Kolomogorov model is used, from which the kinetic constant of the hydriding process is determined.


Detalles Bibliográficos
2021
Agencia Nacional de Investigación e Innovación
Metal hydrides
Hydrogen
Energy storage
Heat transfer
Absorption
Kinetic model
Ciencias Naturales y Exactas
Ciencias Químicas
Físico-Química, Ciencia de los Polímeros, Electroquímica
Inglés
Agencia Nacional de Investigación e Innovación
REDI
https://hdl.handle.net/20.500.12381/637
https://doi.org/10.1016/j.ijhydene.2021.07.207
Acceso abierto
Dedicación de Dominio Público 1.0 Universal. (CC0)
Resumen:
Sumario:Hydrogen storage in metal hydrides presents distinct challenges which encourage the study of effective heat management strategies. Hydrogen absorption in metal hydrides is an exothermic reaction, consequently the generated heat must be removed effectively to achieve the desired performance. This work presents a mathematical model describing the adsorption of hydrogen in La Ni4.7Co0.3 metal hydride as a storage material. Heat and mass transfer effects are modeled in detail. The effect of heat transfer coefficient is also estimated. Besides, a heat transfer fluid for cooling is incorporated to the model. The problem is mathematically formulated presenting a numerical simulation of a design of a cylindrical tank for hydrogen storage. The alloy is studied by using pressure-composition-temperature curves which are carried out at different temperatures. Thermodynamic parameters and hydrogen storage capacity are determined. For isotherm's kinetics, the Jonhson-Mehl-Avrami-Kolomogorov model is used, from which the kinetic constant of the hydriding process is determined.