Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana.
Resumen:
Bixa orellana is a plant that has a variety of uses, such as applications in the food and cosmetic industries, as well as culinary uses, and body painting for Indigenous people. Despite its versatility, few studies have explored its inorganic composition, and its sulfur chemical speciation has only been assessed from the point of view of sulfurous amino acids. Here, we report on the inorganic composition of Bixa orellana fruits, pericarps, and seeds obtained using Wavelength Dispersive X-ray Fluorescence (WD-XRF) and sulfur chemical speciation using X-ray Absorption Near-Edge Structure (XANES). Our results show that the seed is a source of potassium, calcium, magnesium, and phosphorous. But also, the pericarp, which is considered waste, contains a high amount of nutrients. From the XANES measurements, the distribution of the oxidation state of the sulfur atom was obtained, and it was shown that although several oxidation states of sulfur are present, oxidized sulfur (sulfate) is the dominant form of sulfur in all samples.
| 2024 | |
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Bixa orellana WD-XRF Sulfur chemical speciation |
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| Inglés | |
| Universidad de la República | |
| COLIBRI | |
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https://hdl.handle.net/20.500.12008/45872
https://doi.org/10.3390/app14177827 |
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| Acceso abierto | |
| Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0) |
| _version_ | 1872865442605826048 |
|---|---|
| author | Cáceres Gonzalez, Joselaine |
| author2 | Simões, Grazieli Bernini, Rafael B. Coutinho, Lucia H. Nunez, Cecilia Veronica Ferreira, Cristiane S. de Souza, Gerardo Gerson B. |
| author2_role | author author author author author author |
| author_facet | Cáceres Gonzalez, Joselaine Simões, Grazieli Bernini, Rafael B. Coutinho, Lucia H. Nunez, Cecilia Veronica Ferreira, Cristiane S. de Souza, Gerardo Gerson B. |
| author_role | author |
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| collection | COLIBRI |
| dc.contributor.filiacion.none.fl_str_mv | Cáceres Gonzalez Joselaine, Universidad de la República (Uruguay). Facultad de Ingeniería. Simões Grazieli, Federal University of Rio de Janeiro (Brasil). Institute of Chemistry. Bernini Rafael B., Federal Institute of Rio de Janeiro (Brasil). Coutinho Lucia H., Federal University of Rio de Janeiro (Brasil). Institute of Physics. Nunez Cecilia Veronica, National Institute of Amazonian Research (Brasil). Bioprospection and Biotechnology Laboratory. Ferreira Cristiane S., University of Brasilia (Brasil). Department of Botany. de Souza Gerardo Gerson B., Federal University of Rio de Janeiro (Brasil). Institute of Chemistry. |
| dc.creator.none.fl_str_mv | Cáceres Gonzalez, Joselaine Simões, Grazieli Bernini, Rafael B. Coutinho, Lucia H. Nunez, Cecilia Veronica Ferreira, Cristiane S. de Souza, Gerardo Gerson B. |
| dc.date.accessioned.none.fl_str_mv | 2024-09-13T14:48:16Z |
| dc.date.available.none.fl_str_mv | 2024-09-13T14:48:16Z |
| dc.date.issued.none.fl_str_mv | 2024 |
| dc.description.abstract.none.fl_txt_mv | Bixa orellana is a plant that has a variety of uses, such as applications in the food and cosmetic industries, as well as culinary uses, and body painting for Indigenous people. Despite its versatility, few studies have explored its inorganic composition, and its sulfur chemical speciation has only been assessed from the point of view of sulfurous amino acids. Here, we report on the inorganic composition of Bixa orellana fruits, pericarps, and seeds obtained using Wavelength Dispersive X-ray Fluorescence (WD-XRF) and sulfur chemical speciation using X-ray Absorption Near-Edge Structure (XANES). Our results show that the seed is a source of potassium, calcium, magnesium, and phosphorous. But also, the pericarp, which is considered waste, contains a high amount of nutrients. From the XANES measurements, the distribution of the oxidation state of the sulfur atom was obtained, and it was shown that although several oxidation states of sulfur are present, oxidized sulfur (sulfate) is the dominant form of sulfur in all samples. |
| dc.format.mimetype.es.fl_str_mv | application/pdf |
| dc.identifier.citation.es.fl_str_mv | Cáceres Gonzalez, J., Simões, G., Bernini, R. y otros. "Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana". Appl. Sci. [en línea] 2024, vol. 14, no. 17. DOI: https://doi.org/10.3390/app14177827 |
| dc.identifier.doi.none.fl_str_mv | https://doi.org/10.3390/app14177827 |
| dc.identifier.uri.none.fl_str_mv | https://hdl.handle.net/20.500.12008/45872 |
| dc.language.iso.none.fl_str_mv | en eng |
| dc.publisher.es.fl_str_mv | MDPI |
| dc.relation.none.fl_str_mv | Applied Sciences, vol. 14, no. 17, 2024, 7827. |
| dc.rights.license.none.fl_str_mv | Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0) |
| dc.rights.none.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.source.none.fl_str_mv | reponame:COLIBRI instname:Universidad de la República instacron:Universidad de la República |
| dc.subject.es.fl_str_mv | Bixa orellana WD-XRF Sulfur chemical speciation |
| dc.title.none.fl_str_mv | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. |
| dc.type.es.fl_str_mv | Artículo |
| dc.type.none.fl_str_mv | info:eu-repo/semantics/article |
| dc.type.version.none.fl_str_mv | info:eu-repo/semantics/publishedVersion |
| description | Bixa orellana is a plant that has a variety of uses, such as applications in the food and cosmetic industries, as well as culinary uses, and body painting for Indigenous people. Despite its versatility, few studies have explored its inorganic composition, and its sulfur chemical speciation has only been assessed from the point of view of sulfurous amino acids. Here, we report on the inorganic composition of Bixa orellana fruits, pericarps, and seeds obtained using Wavelength Dispersive X-ray Fluorescence (WD-XRF) and sulfur chemical speciation using X-ray Absorption Near-Edge Structure (XANES). Our results show that the seed is a source of potassium, calcium, magnesium, and phosphorous. But also, the pericarp, which is considered waste, contains a high amount of nutrients. From the XANES measurements, the distribution of the oxidation state of the sulfur atom was obtained, and it was shown that although several oxidation states of sulfur are present, oxidized sulfur (sulfate) is the dominant form of sulfur in all samples. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | COLIBRI_a7bb25398d6d5b83ff1cc22c88477633 |
| identifier_str_mv | Cáceres Gonzalez, J., Simões, G., Bernini, R. y otros. "Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana". Appl. Sci. [en línea] 2024, vol. 14, no. 17. DOI: https://doi.org/10.3390/app14177827 |
| instacron_str | Universidad de la República |
| institution | Universidad de la República |
| instname_str | Universidad de la República |
| language | eng |
| language_invalid_str_mv | en |
| network_acronym_str | COLIBRI |
| network_name_str | COLIBRI |
| oai_identifier_str | oai:colibri.udelar.edu.uy:20.500.12008/45872 |
| publishDate | 2024 |
| reponame_str | COLIBRI |
| repository.mail.fl_str_mv | karina.camps@seciu.edu.uy |
| repository.name.fl_str_mv | COLIBRI - Universidad de la República |
| repository_id_str | 4771 |
| rights_invalid_str_mv | Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0) |
| spelling | Cáceres Gonzalez Joselaine, Universidad de la República (Uruguay). Facultad de Ingeniería.Simões Grazieli, Federal University of Rio de Janeiro (Brasil). Institute of Chemistry.Bernini Rafael B., Federal Institute of Rio de Janeiro (Brasil).Coutinho Lucia H., Federal University of Rio de Janeiro (Brasil). Institute of Physics.Nunez Cecilia Veronica, National Institute of Amazonian Research (Brasil). Bioprospection and Biotechnology Laboratory.Ferreira Cristiane S., University of Brasilia (Brasil). Department of Botany.de Souza Gerardo Gerson B., Federal University of Rio de Janeiro (Brasil). Institute of Chemistry.2024-09-13T14:48:16Z2024-09-13T14:48:16Z2024Cáceres Gonzalez, J., Simões, G., Bernini, R. y otros. "Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana". Appl. Sci. [en línea] 2024, vol. 14, no. 17. DOI: https://doi.org/10.3390/app14177827https://hdl.handle.net/20.500.12008/45872https://doi.org/10.3390/app14177827Bixa orellana is a plant that has a variety of uses, such as applications in the food and cosmetic industries, as well as culinary uses, and body painting for Indigenous people. Despite its versatility, few studies have explored its inorganic composition, and its sulfur chemical speciation has only been assessed from the point of view of sulfurous amino acids. Here, we report on the inorganic composition of Bixa orellana fruits, pericarps, and seeds obtained using Wavelength Dispersive X-ray Fluorescence (WD-XRF) and sulfur chemical speciation using X-ray Absorption Near-Edge Structure (XANES). Our results show that the seed is a source of potassium, calcium, magnesium, and phosphorous. But also, the pericarp, which is considered waste, contains a high amount of nutrients. From the XANES measurements, the distribution of the oxidation state of the sulfur atom was obtained, and it was shown that although several oxidation states of sulfur are present, oxidized sulfur (sulfate) is the dominant form of sulfur in all samples.Submitted by Berón Cecilia (cberon@fing.edu.uy) on 2024-09-12T17:01:14Z No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) CSBCNFS24.pdf: 935879 bytes, checksum: c062380ba02caa9955dbf03e4485d674 (MD5)Approved for entry into archive by Machado Jimena (jmachado@fing.edu.uy) on 2024-09-13T13:33:49Z (GMT) No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) CSBCNFS24.pdf: 935879 bytes, checksum: c062380ba02caa9955dbf03e4485d674 (MD5)Made available in DSpace by Luna Fabiana (fabiana.luna@seciu.edu.uy) on 2024-09-13T14:48:16Z (GMT). No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) CSBCNFS24.pdf: 935879 bytes, checksum: c062380ba02caa9955dbf03e4485d674 (MD5) Previous issue date: 2024application/pdfenengMDPIApplied Sciences, vol. 14, no. 17, 2024, 7827.Las obras depositadas en el Repositorio se rigen por la Ordenanza de los Derechos de la Propiedad Intelectual de la Universidad de la República.(Res. Nº 91 de C.D.C. de 8/III/1994 – D.O. 7/IV/1994) y por la Ordenanza del Repositorio Abierto de la Universidad de la República (Res. Nº 16 de C.D.C. de 07/10/2014)info:eu-repo/semantics/openAccessLicencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0)Bixa orellanaWD-XRFSulfur chemical speciationApplication of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana.Artículoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionreponame:COLIBRIinstname:Universidad de la Repúblicainstacron:Universidad de la RepúblicaCáceres Gonzalez, JoselaineSimões, GrazieliBernini, Rafael B.Coutinho, Lucia H.Nunez, Cecilia VeronicaFerreira, Cristiane S.de Souza, Gerardo Gerson B.LICENSElicense.txtlicense.txttext/plain; charset=utf-84267http://localhost:8080/xmlui/bitstream/20.500.12008/45872/5/license.txt6429389a7df7277b72b7924fdc7d47a9MD55CC-LICENSElicense_urllicense_urltext/plain; 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públicahttps://udelar.edu.uy/https://www.colibri.udelar.edu.uy/oai/requestkarina.camps@seciu.edu.uyUruguayopendoar:47712024-09-13T14:48:16COLIBRI - Universidad de la Repúblicafalse |
| spellingShingle | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. Cáceres Gonzalez, Joselaine Bixa orellana WD-XRF Sulfur chemical speciation |
| status_str | publishedVersion |
| title | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. |
| title_full | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. |
| title_fullStr | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. |
| title_full_unstemmed | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. |
| title_short | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. |
| title_sort | Application of x-ray spectroscopic techniques to determine the inorganic composition and sulfur chemical speciation of the amazonian plant bixa orellana. |
| topic | Bixa orellana WD-XRF Sulfur chemical speciation |
| url | https://hdl.handle.net/20.500.12008/45872 https://doi.org/10.3390/app14177827 |
