CO2 capture from industrial plants for the production of marketable compounds.

Gonzalez Sotelo, Valeria

Supervisor(es): Torres, Ana Inés - Corengia, Mariana

Resumen:

Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies.

Detalles Bibliográficos
2024
Process design
Carbon capture and utilization
Electrochemical cell
Inglés
Universidad de la República
COLIBRI
https://hdl.handle.net/20.500.12008/42954
Acceso abierto
Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0)
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author Gonzalez Sotelo, Valeria
author_facet Gonzalez Sotelo, Valeria
author_role author
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collection COLIBRI
dc.contributor.filiacion.none.fl_str_mv Gonzalez Sotelo Valeria, Universidad de la República (Uruguay). Facultad de Ingeniería.
dc.creator.advisor.none.fl_str_mv Torres, Ana Inés
Corengia, Mariana
dc.creator.none.fl_str_mv Gonzalez Sotelo, Valeria
dc.date.accessioned.none.fl_str_mv 2024-03-05T17:36:50Z
dc.date.available.none.fl_str_mv 2024-03-05T17:36:50Z
dc.date.issued.none.fl_str_mv 2024
dc.description.abstract.none.fl_txt_mv Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies.
dc.format.extent.es.fl_str_mv 118 p.
dc.format.mimetype.es.fl_str_mv application/pdf
dc.identifier.citation.es.fl_str_mv Gonzalez Sotelo, V. CO2 capture from industrial plants for the production of marketable compounds [en línea] Tesis de maestría. Montevideo: Udelar. FI. IIQ, 2024.
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12008/42954
dc.language.iso.none.fl_str_mv en_US
eng
dc.publisher.es.fl_str_mv Udelar. FI.
dc.rights.license.none.fl_str_mv Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0)
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.source.none.fl_str_mv reponame:COLIBRI
instname:Universidad de la República
instacron:Universidad de la República
dc.subject.es.fl_str_mv Process design
Carbon capture and utilization
Electrochemical cell
dc.title.none.fl_str_mv CO2 capture from industrial plants for the production of marketable compounds.
dc.type.es.fl_str_mv Tesis de maestría
dc.type.none.fl_str_mv info:eu-repo/semantics/masterThesis
dc.type.version.none.fl_str_mv info:eu-repo/semantics/acceptedVersion
description Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies.
eu_rights_str_mv openAccess
format masterThesis
id COLIBRI_97249d7b3fcce9fa04868b431d6509cd
identifier_str_mv Gonzalez Sotelo, V. CO2 capture from industrial plants for the production of marketable compounds [en línea] Tesis de maestría. Montevideo: Udelar. FI. IIQ, 2024.
instacron_str Universidad de la República
institution Universidad de la República
instname_str Universidad de la República
language eng
language_invalid_str_mv en_US
network_acronym_str COLIBRI
network_name_str COLIBRI
oai_identifier_str oai:colibri.udelar.edu.uy:20.500.12008/42954
publishDate 2024
reponame_str COLIBRI
repository.mail.fl_str_mv karina.camps@seciu.edu.uy
repository.name.fl_str_mv COLIBRI - Universidad de la República
repository_id_str 4771
rights_invalid_str_mv Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0)
spelling Gonzalez Sotelo Valeria, Universidad de la República (Uruguay). Facultad de Ingeniería.2024-03-05T17:36:50Z2024-03-05T17:36:50Z2024Gonzalez Sotelo, V. CO2 capture from industrial plants for the production of marketable compounds [en línea] Tesis de maestría. Montevideo: Udelar. FI. IIQ, 2024.https://hdl.handle.net/20.500.12008/42954Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies.Submitted by Berón Cecilia (cberon@fing.edu.uy) on 2024-03-05T17:09:27Z No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) Gon24.pdf: 4018139 bytes, checksum: ba3a7dae8708f00e6d9a642bb90c3c24 (MD5)Approved for entry into archive by Machado Jimena (jmachado@fing.edu.uy) on 2024-03-05T17:22:30Z (GMT) No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) Gon24.pdf: 4018139 bytes, checksum: ba3a7dae8708f00e6d9a642bb90c3c24 (MD5)Made available in DSpace by Luna Fabiana (fabiana.luna@seciu.edu.uy) on 2024-03-05T17:36:50Z (GMT). No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) Gon24.pdf: 4018139 bytes, checksum: ba3a7dae8708f00e6d9a642bb90c3c24 (MD5) Previous issue date: 2024118 p.application/pdfen_USengUdelar. FI.Las obras depositadas en el Repositorio se rigen por la Ordenanza de los Derechos de la Propiedad Intelectual de la Universidad de la República.(Res. Nº 91 de C.D.C. de 8/III/1994 – D.O. 7/IV/1994) y por la Ordenanza del Repositorio Abierto de la Universidad de la República (Res. Nº 16 de C.D.C. de 07/10/2014)info:eu-repo/semantics/openAccessLicencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0)Process designCarbon capture and utilizationElectrochemical cellCO2 capture from industrial plants for the production of marketable compounds.Tesis de maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionreponame:COLIBRIinstname:Universidad de la Repúblicainstacron:Universidad de la RepúblicaGonzalez Sotelo, ValeriaTorres, Ana InésCorengia, MarianaUniversidad de la República (Uruguay). 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- Universidad de la Repúblicafalse
spellingShingle CO2 capture from industrial plants for the production of marketable compounds.
Gonzalez Sotelo, Valeria
Process design
Carbon capture and utilization
Electrochemical cell
status_str acceptedVersion
title CO2 capture from industrial plants for the production of marketable compounds.
title_full CO2 capture from industrial plants for the production of marketable compounds.
title_fullStr CO2 capture from industrial plants for the production of marketable compounds.
title_full_unstemmed CO2 capture from industrial plants for the production of marketable compounds.
title_short CO2 capture from industrial plants for the production of marketable compounds.
title_sort CO2 capture from industrial plants for the production of marketable compounds.
topic Process design
Carbon capture and utilization
Electrochemical cell
url https://hdl.handle.net/20.500.12008/42954