CO2 capture from industrial plants for the production of marketable compounds.
Supervisor(es): Torres, Ana Inés - Corengia, Mariana
Resumen:
Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies.
| 2024 | |
|
Process design Carbon capture and utilization Electrochemical cell |
|
| Inglés | |
| Universidad de la República | |
| COLIBRI | |
| https://hdl.handle.net/20.500.12008/42954 | |
| Acceso abierto | |
| Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0) |
| _version_ | 1877554986417651712 |
|---|---|
| author | Gonzalez Sotelo, Valeria |
| author_facet | Gonzalez Sotelo, Valeria |
| author_role | author |
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| collection | COLIBRI |
| dc.contributor.filiacion.none.fl_str_mv | Gonzalez Sotelo Valeria, Universidad de la República (Uruguay). Facultad de Ingeniería. |
| dc.creator.advisor.none.fl_str_mv | Torres, Ana Inés Corengia, Mariana |
| dc.creator.none.fl_str_mv | Gonzalez Sotelo, Valeria |
| dc.date.accessioned.none.fl_str_mv | 2024-03-05T17:36:50Z |
| dc.date.available.none.fl_str_mv | 2024-03-05T17:36:50Z |
| dc.date.issued.none.fl_str_mv | 2024 |
| dc.description.abstract.none.fl_txt_mv | Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies. |
| dc.format.extent.es.fl_str_mv | 118 p. |
| dc.format.mimetype.es.fl_str_mv | application/pdf |
| dc.identifier.citation.es.fl_str_mv | Gonzalez Sotelo, V. CO2 capture from industrial plants for the production of marketable compounds [en línea] Tesis de maestría. Montevideo: Udelar. FI. IIQ, 2024. |
| dc.identifier.uri.none.fl_str_mv | https://hdl.handle.net/20.500.12008/42954 |
| dc.language.iso.none.fl_str_mv | en_US eng |
| dc.publisher.es.fl_str_mv | Udelar. FI. |
| dc.rights.license.none.fl_str_mv | Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0) |
| dc.rights.none.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.source.none.fl_str_mv | reponame:COLIBRI instname:Universidad de la República instacron:Universidad de la República |
| dc.subject.es.fl_str_mv | Process design Carbon capture and utilization Electrochemical cell |
| dc.title.none.fl_str_mv | CO2 capture from industrial plants for the production of marketable compounds. |
| dc.type.es.fl_str_mv | Tesis de maestría |
| dc.type.none.fl_str_mv | info:eu-repo/semantics/masterThesis |
| dc.type.version.none.fl_str_mv | info:eu-repo/semantics/acceptedVersion |
| description | Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies. |
| eu_rights_str_mv | openAccess |
| format | masterThesis |
| id | COLIBRI_97249d7b3fcce9fa04868b431d6509cd |
| identifier_str_mv | Gonzalez Sotelo, V. CO2 capture from industrial plants for the production of marketable compounds [en línea] Tesis de maestría. Montevideo: Udelar. FI. IIQ, 2024. |
| instacron_str | Universidad de la República |
| institution | Universidad de la República |
| instname_str | Universidad de la República |
| language | eng |
| language_invalid_str_mv | en_US |
| network_acronym_str | COLIBRI |
| network_name_str | COLIBRI |
| oai_identifier_str | oai:colibri.udelar.edu.uy:20.500.12008/42954 |
| publishDate | 2024 |
| reponame_str | COLIBRI |
| repository.mail.fl_str_mv | karina.camps@seciu.edu.uy |
| repository.name.fl_str_mv | COLIBRI - Universidad de la República |
| repository_id_str | 4771 |
| rights_invalid_str_mv | Licencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0) |
| spelling | Gonzalez Sotelo Valeria, Universidad de la República (Uruguay). Facultad de Ingeniería.2024-03-05T17:36:50Z2024-03-05T17:36:50Z2024Gonzalez Sotelo, V. CO2 capture from industrial plants for the production of marketable compounds [en línea] Tesis de maestría. Montevideo: Udelar. FI. IIQ, 2024.https://hdl.handle.net/20.500.12008/42954Carbon Dioxide Reduction (CO2R) is gaining attention as a way to reduce carbon in the environment, especially by turning industrial CO2 emissions into valuable chemicals and fuels. However, the methods to achieve this are still in early development stages. Moreover, there is a lack of process design and techno-economic feasibility studies to assess competitiveness, select the most promising alternatives, and identify research and development gaps. The main goals of this thesis are to create a mathematical model for the CO2R electrochemical cell, study the effects of different operating conditions on the cell’s performance, and design a complete process for turning CO2 into valuable chemicals and fuels. An electrochemical cell model is developed in MATLAB, which incorporates fundamental phenomena inside each part of the cell, such as species and charge transport, charge conservation, and electrochemical reactions. Aspen Plus is then used to study the overall process, including the reaction and the separation stages. Two case studies are presented: one producing methanol, CO, and H2, and the other producing a variety of chemicals including ethanol and ethylene. Detailed models and simulations were performed for each case, leading to a thorough economic analysis. The economic analysis shows a large difference in the minimum estimated selling price between the two case studies, with the production of mixed chemicals being more economical. A main challenge identified is the low concentration of products at the end of the reaction step, which increases the energy needed for separation. The study also finds that the applied voltage plays a crucial role in influencing both product production rates and selectivity in the CO2R process. The flexible models developed in this research can serve as valuable tools for testing different electrolyzer operating conditions, catalysts, and reactions, all of which have an impact on subsequent separation costs. In summary, this study represents a valuable resource for the assessment of CO2R technologies.Submitted by Berón Cecilia (cberon@fing.edu.uy) on 2024-03-05T17:09:27Z No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) Gon24.pdf: 4018139 bytes, checksum: ba3a7dae8708f00e6d9a642bb90c3c24 (MD5)Approved for entry into archive by Machado Jimena (jmachado@fing.edu.uy) on 2024-03-05T17:22:30Z (GMT) No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) Gon24.pdf: 4018139 bytes, checksum: ba3a7dae8708f00e6d9a642bb90c3c24 (MD5)Made available in DSpace by Luna Fabiana (fabiana.luna@seciu.edu.uy) on 2024-03-05T17:36:50Z (GMT). No. of bitstreams: 2 license_rdf: 25790 bytes, checksum: 489f03e71d39068f329bdec8798bce58 (MD5) Gon24.pdf: 4018139 bytes, checksum: ba3a7dae8708f00e6d9a642bb90c3c24 (MD5) Previous issue date: 2024118 p.application/pdfen_USengUdelar. FI.Las obras depositadas en el Repositorio se rigen por la Ordenanza de los Derechos de la Propiedad Intelectual de la Universidad de la República.(Res. Nº 91 de C.D.C. de 8/III/1994 – D.O. 7/IV/1994) y por la Ordenanza del Repositorio Abierto de la Universidad de la República (Res. Nº 16 de C.D.C. de 07/10/2014)info:eu-repo/semantics/openAccessLicencia Creative Commons Atribución - No Comercial - Sin Derivadas (CC - By-NC-ND 4.0)Process designCarbon capture and utilizationElectrochemical cellCO2 capture from industrial plants for the production of marketable compounds.Tesis de maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionreponame:COLIBRIinstname:Universidad de la Repúblicainstacron:Universidad de la RepúblicaGonzalez Sotelo, ValeriaTorres, Ana InésCorengia, MarianaUniversidad de la República (Uruguay). 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- Universidad de la Repúblicafalse |
| spellingShingle | CO2 capture from industrial plants for the production of marketable compounds. Gonzalez Sotelo, Valeria Process design Carbon capture and utilization Electrochemical cell |
| status_str | acceptedVersion |
| title | CO2 capture from industrial plants for the production of marketable compounds. |
| title_full | CO2 capture from industrial plants for the production of marketable compounds. |
| title_fullStr | CO2 capture from industrial plants for the production of marketable compounds. |
| title_full_unstemmed | CO2 capture from industrial plants for the production of marketable compounds. |
| title_short | CO2 capture from industrial plants for the production of marketable compounds. |
| title_sort | CO2 capture from industrial plants for the production of marketable compounds. |
| topic | Process design Carbon capture and utilization Electrochemical cell |
| url | https://hdl.handle.net/20.500.12008/42954 |