Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode

Marcuzzo, Jossano Saldanha - Cuña, Andrés - Tancredi, Néstor - Méndez, Eduardo - Bernardi, Heide Heloise - Baldan, Mauricio Ribeiro

Resumen:

Activated carbon fibers (ACF) are known as excellent adsorbent materials due to their fast adsorption rate and easy handling characteristic. The ACF can be manufactured from the polyacrylonitrile fiber, based on an usual carbon fibers (CF) production process accomplished by an additional activation process. The aim of the present work is to describe the production, chemical/morphological characterization and application potentiality of activated carbon fiber felt (ACFF) produced from textile PAN fiber, using a set of homemade equipment. The 5.0 dtex PAN fiber tow with 200 thousand filaments was oxidized and used as raw material for felt production. The oxidized PAN fiber felt (OPFF) was displaced in a special sample holder, carbonized (900 °C) and then activated in CO2 atmosphere at 1000 °C in an electric tubular furnace. All steps of the process were performed as fast as possible, and characterization was done by 77 K N2 isotherms, adsorption isotherms in liquid phase, scanning electronic microscope, X-ray diffraction and surface chemistry by Bhoem methodology. The results confirmed the production of essentially microporous (pore < 3.2 nm, centered on 1.2 nm) and 1,300 m2 g-1 surface area. The ACFF produced have demonstrated a strong potential application as electrode supercapacitor.


Detalles Bibliográficos
2016
Activated carbon fiber
Activated felt
Supercapacitor electrodes
Inglés
Universidad de la República
COLIBRI
https://hdl.handle.net/20.500.12008/26303
Acceso abierto
Licencia Creative Commons Atribución (CC - By 4.0)
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author Marcuzzo, Jossano Saldanha
author2 Cuña, Andrés
Tancredi, Néstor
Méndez, Eduardo
Bernardi, Heide Heloise
Baldan, Mauricio Ribeiro
author2_role author
author
author
author
author
author_facet Marcuzzo, Jossano Saldanha
Cuña, Andrés
Tancredi, Néstor
Méndez, Eduardo
Bernardi, Heide Heloise
Baldan, Mauricio Ribeiro
author_role author
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collection COLIBRI
dc.contributor.filiacion.none.fl_str_mv Marcuzzo Jossano Saldanha
Cuña Andres, Universidad de la República (Uruguay). Facultad de Química
Tancredi Nestor, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Física
Mendez Eduardo, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Química Biológica
Bernardi Heide Heloise
Baldan Mauricio Ribeiro
dc.creator.none.fl_str_mv Marcuzzo, Jossano Saldanha
Cuña, Andrés
Tancredi, Néstor
Méndez, Eduardo
Bernardi, Heide Heloise
Baldan, Mauricio Ribeiro
dc.date.accessioned.none.fl_str_mv 2021-01-11T15:19:03Z
dc.date.available.none.fl_str_mv 2021-01-11T15:19:03Z
dc.date.issued.none.fl_str_mv 2016
dc.description.abstract.none.fl_txt_mv Activated carbon fibers (ACF) are known as excellent adsorbent materials due to their fast adsorption rate and easy handling characteristic. The ACF can be manufactured from the polyacrylonitrile fiber, based on an usual carbon fibers (CF) production process accomplished by an additional activation process. The aim of the present work is to describe the production, chemical/morphological characterization and application potentiality of activated carbon fiber felt (ACFF) produced from textile PAN fiber, using a set of homemade equipment. The 5.0 dtex PAN fiber tow with 200 thousand filaments was oxidized and used as raw material for felt production. The oxidized PAN fiber felt (OPFF) was displaced in a special sample holder, carbonized (900 °C) and then activated in CO2 atmosphere at 1000 °C in an electric tubular furnace. All steps of the process were performed as fast as possible, and characterization was done by 77 K N2 isotherms, adsorption isotherms in liquid phase, scanning electronic microscope, X-ray diffraction and surface chemistry by Bhoem methodology. The results confirmed the production of essentially microporous (pore < 3.2 nm, centered on 1.2 nm) and 1,300 m2 g-1 surface area. The ACFF produced have demonstrated a strong potential application as electrode supercapacitor.
dc.format.extent.es.fl_str_mv 6 h.
dc.format.mimetype.es.fl_str_mv application/pdf
dc.identifier.citation.es.fl_str_mv Marcuzzo, J, Cuña, A, Tancredi, N, y otros. "Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode". Revista Brasileira de Aplicações de Vácuo. [en línea] 2016, 35 (2) pp. 58-63. 6 h. doi: 10.17563/rbav.v35i2.1022
dc.identifier.issn.none.fl_str_mv 1983-4047
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12008/26303
dc.language.iso.none.fl_str_mv en_US
eng
dc.publisher.en.fl_str_mv Brazilian Vacum Society
dc.relation.ispartof.es.fl_str_mv Revista Brasileira de Aplicações de Vácuo, 2016, 35 (2) pp. 58-63.
dc.rights.license.none.fl_str_mv Licencia Creative Commons Atribución (CC - By 4.0)
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.source.none.fl_str_mv reponame:COLIBRI
instname:Universidad de la República
instacron:Universidad de la República
dc.subject.en.fl_str_mv Activated carbon fiber
Activated felt
Supercapacitor electrodes
dc.title.none.fl_str_mv Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
dc.type.es.fl_str_mv Artículo
dc.type.none.fl_str_mv info:eu-repo/semantics/article
dc.type.version.none.fl_str_mv info:eu-repo/semantics/publishedVersion
description Activated carbon fibers (ACF) are known as excellent adsorbent materials due to their fast adsorption rate and easy handling characteristic. The ACF can be manufactured from the polyacrylonitrile fiber, based on an usual carbon fibers (CF) production process accomplished by an additional activation process. The aim of the present work is to describe the production, chemical/morphological characterization and application potentiality of activated carbon fiber felt (ACFF) produced from textile PAN fiber, using a set of homemade equipment. The 5.0 dtex PAN fiber tow with 200 thousand filaments was oxidized and used as raw material for felt production. The oxidized PAN fiber felt (OPFF) was displaced in a special sample holder, carbonized (900 °C) and then activated in CO2 atmosphere at 1000 °C in an electric tubular furnace. All steps of the process were performed as fast as possible, and characterization was done by 77 K N2 isotherms, adsorption isotherms in liquid phase, scanning electronic microscope, X-ray diffraction and surface chemistry by Bhoem methodology. The results confirmed the production of essentially microporous (pore < 3.2 nm, centered on 1.2 nm) and 1,300 m2 g-1 surface area. The ACFF produced have demonstrated a strong potential application as electrode supercapacitor.
eu_rights_str_mv openAccess
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identifier_str_mv Marcuzzo, J, Cuña, A, Tancredi, N, y otros. "Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode". Revista Brasileira de Aplicações de Vácuo. [en línea] 2016, 35 (2) pp. 58-63. 6 h. doi: 10.17563/rbav.v35i2.1022
1983-4047
instacron_str Universidad de la República
institution Universidad de la República
instname_str Universidad de la República
language eng
language_invalid_str_mv en_US
network_acronym_str COLIBRI
network_name_str COLIBRI
oai_identifier_str oai:colibri.udelar.edu.uy:20.500.12008/26303
publishDate 2016
reponame_str COLIBRI
repository.mail.fl_str_mv mabel.seroubian@seciu.edu.uy
repository.name.fl_str_mv COLIBRI - Universidad de la República
repository_id_str 4771
rights_invalid_str_mv Licencia Creative Commons Atribución (CC - By 4.0)
spelling Marcuzzo Jossano SaldanhaCuña Andres, Universidad de la República (Uruguay). Facultad de QuímicaTancredi Nestor, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de FísicaMendez Eduardo, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Química BiológicaBernardi Heide HeloiseBaldan Mauricio Ribeiro2021-01-11T15:19:03Z2021-01-11T15:19:03Z2016Marcuzzo, J, Cuña, A, Tancredi, N, y otros. "Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode". Revista Brasileira de Aplicações de Vácuo. [en línea] 2016, 35 (2) pp. 58-63. 6 h. doi: 10.17563/rbav.v35i2.10221983-4047https://hdl.handle.net/20.500.12008/26303Activated carbon fibers (ACF) are known as excellent adsorbent materials due to their fast adsorption rate and easy handling characteristic. The ACF can be manufactured from the polyacrylonitrile fiber, based on an usual carbon fibers (CF) production process accomplished by an additional activation process. The aim of the present work is to describe the production, chemical/morphological characterization and application potentiality of activated carbon fiber felt (ACFF) produced from textile PAN fiber, using a set of homemade equipment. The 5.0 dtex PAN fiber tow with 200 thousand filaments was oxidized and used as raw material for felt production. The oxidized PAN fiber felt (OPFF) was displaced in a special sample holder, carbonized (900 °C) and then activated in CO2 atmosphere at 1000 °C in an electric tubular furnace. All steps of the process were performed as fast as possible, and characterization was done by 77 K N2 isotherms, adsorption isotherms in liquid phase, scanning electronic microscope, X-ray diffraction and surface chemistry by Bhoem methodology. The results confirmed the production of essentially microporous (pore < 3.2 nm, centered on 1.2 nm) and 1,300 m2 g-1 surface area. The ACFF produced have demonstrated a strong potential application as electrode supercapacitor.Submitted by Parodi Mónica (mparodi@fcien.edu.uy) on 2021-01-07T18:33:11Z No. of bitstreams: 2 license_rdf: 19875 bytes, checksum: 9fdbed07f52437945402c4e70fa4773e (MD5) 1017563rbavv35i21022.pdf: 1454652 bytes, checksum: 46e276c5a0ad14719e976bf6151e7d83 (MD5)Approved for entry into archive by Faget Cecilia (lfaget@fcien.edu.uy) on 2021-01-11T15:13:55Z (GMT) No. of bitstreams: 2 license_rdf: 19875 bytes, checksum: 9fdbed07f52437945402c4e70fa4773e (MD5) 1017563rbavv35i21022.pdf: 1454652 bytes, checksum: 46e276c5a0ad14719e976bf6151e7d83 (MD5)Made available in DSpace by Luna Fabiana (fabiana.luna@fic.edu.uy) on 2021-01-11T15:19:03Z (GMT). No. of bitstreams: 2 license_rdf: 19875 bytes, checksum: 9fdbed07f52437945402c4e70fa4773e (MD5) 1017563rbavv35i21022.pdf: 1454652 bytes, checksum: 46e276c5a0ad14719e976bf6151e7d83 (MD5) Previous issue date: 20166 h.application/pdfen_USengBrazilian Vacum SocietyRevista Brasileira de Aplicações de Vácuo, 2016, 35 (2) pp. 58-63.Las obras depositadas en el Repositorio se rigen por la Ordenanza de los Derechos de la Propiedad Intelectual de la Universidad de la República.(Res. Nº 91 de C.D.C. de 8/III/1994 – D.O. 7/IV/1994) y por la Ordenanza del Repositorio Abierto de la Universidad de la República (Res. Nº 16 de C.D.C. de 07/10/2014)info:eu-repo/semantics/openAccessLicencia Creative Commons Atribución (CC - By 4.0)Activated carbon fiberActivated feltSupercapacitor electrodesMicroporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrodeArtículoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionreponame:COLIBRIinstname:Universidad de la Repúblicainstacron:Universidad de la RepúblicaMarcuzzo, Jossano SaldanhaCuña, AndrésTancredi, NéstorMéndez, EduardoBernardi, Heide HeloiseBaldan, Mauricio RibeiroLICENSElicense.txtlicense.txttext/plain; charset=utf-84267http://localhost:8080/xmlui/bitstream/20.500.12008/26303/5/license.txt6429389a7df7277b72b7924fdc7d47a9MD55CC-LICENSElicense_urllicense_urltext/plain; charset=utf-844http://localhost:8080/xmlui/bitstream/20.500.12008/26303/2/license_urla0ebbeafb9d2ec7cbb19d7137ebc392cMD52license_textlicense_texttext/html; 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- Universidad de la Repúblicafalse
spellingShingle Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
Marcuzzo, Jossano Saldanha
Activated carbon fiber
Activated felt
Supercapacitor electrodes
status_str publishedVersion
title Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
title_full Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
title_fullStr Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
title_full_unstemmed Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
title_short Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
title_sort Microporus activated carbon fiber felt from Brazilian textile PAN fiber: preparation, characterization and application as super capacitor electrode
topic Activated carbon fiber
Activated felt
Supercapacitor electrodes
url https://hdl.handle.net/20.500.12008/26303