Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation

Enciso, María Paula - Decoppet, Jean-David - Moehl, Thomas - Grätzel, Michael - Wörner, Michael - Cerdá, María Fernanda

Resumen:

The influence of some coadsorbents and different pH values on the efficiency of DSS cells assembled with phycocyanin was evaluated using quartz crystal microbalance (QCM) and electrochemical techniques as impedance spectroscopy (EIS) and cyclic voltammetry (CV). Chlorophyll, heptadecanoic acid and 7.5 or 8.5 pH values were applied when nanostructured TiO2 electrode was dipped in the dye solution. Best efficiency conversion values were obtained when using fatty acids as coadsorbents, reaching a conversion efficiency of 0.04 % for open cells.


Detalles Bibliográficos
2016
Coadsorbents
DSSC
EIS
Phycocyanin
QCM
Inglés
Universidad de la República
COLIBRI
https://hdl.handle.net/20.500.12008/26307
Acceso abierto
Licencia Creative Commons Atribución (CC - By 4.0)
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author Enciso, María Paula
author2 Decoppet, Jean-David
Moehl, Thomas
Grätzel, Michael
Wörner, Michael
Cerdá, María Fernanda
author2_role author
author
author
author
author
author_facet Enciso, María Paula
Decoppet, Jean-David
Moehl, Thomas
Grätzel, Michael
Wörner, Michael
Cerdá, María Fernanda
author_role author
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collection COLIBRI
dc.contributor.filiacion.none.fl_str_mv Enciso María Paula, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Química Biológica
Decoppet Jean-David, Ecole Polytechnique Federale de Lausanne
Moehl Thomas, Ecole Polytechnique Federale de Lausanne
Grätzel Michael, Ecole Polytechnique Federale de Lausanne
Wörner Michael, Karlsruher Institut für Technologie
Cerdá María Fernanda, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Química Biológica
dc.creator.none.fl_str_mv Enciso, María Paula
Decoppet, Jean-David
Moehl, Thomas
Grätzel, Michael
Wörner, Michael
Cerdá, María Fernanda
dc.date.accessioned.none.fl_str_mv 2021-01-11T15:57:02Z
dc.date.available.none.fl_str_mv 2021-01-11T15:57:02Z
dc.date.issued.none.fl_str_mv 2016
dc.description.abstract.none.fl_txt_mv The influence of some coadsorbents and different pH values on the efficiency of DSS cells assembled with phycocyanin was evaluated using quartz crystal microbalance (QCM) and electrochemical techniques as impedance spectroscopy (EIS) and cyclic voltammetry (CV). Chlorophyll, heptadecanoic acid and 7.5 or 8.5 pH values were applied when nanostructured TiO2 electrode was dipped in the dye solution. Best efficiency conversion values were obtained when using fatty acids as coadsorbents, reaching a conversion efficiency of 0.04 % for open cells.
dc.format.extent.es.fl_str_mv 11 h.
dc.format.mimetype.es.fl_str_mv application/pdf
dc.identifier.citation.es.fl_str_mv Enciso, M, Decoppet, J, Moehl, T, y otros. "Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation". International Journal of Electrochemical Science. [en línea] 2016, 11 (5), pp. 3604-3614. 11 h. doi: 10.20964/110443
dc.identifier.doi.none.fl_str_mv 10.20964/110443
dc.identifier.issn.none.fl_str_mv 1452-3981
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12008/26307
dc.language.iso.none.fl_str_mv en_US
eng
dc.publisher.en.fl_str_mv Electrochemical Science Group
dc.relation.ispartof.en.fl_str_mv International Journal of Electrochemical Science, 2016, 11 (5), pp. 3604-3614.
dc.rights.license.none.fl_str_mv Licencia Creative Commons Atribución (CC - By 4.0)
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.source.none.fl_str_mv reponame:COLIBRI
instname:Universidad de la República
instacron:Universidad de la República
dc.subject.en.fl_str_mv Coadsorbents
DSSC
EIS
Phycocyanin
QCM
dc.title.none.fl_str_mv Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
dc.type.es.fl_str_mv Artículo
dc.type.none.fl_str_mv info:eu-repo/semantics/article
dc.type.version.none.fl_str_mv info:eu-repo/semantics/publishedVersion
description The influence of some coadsorbents and different pH values on the efficiency of DSS cells assembled with phycocyanin was evaluated using quartz crystal microbalance (QCM) and electrochemical techniques as impedance spectroscopy (EIS) and cyclic voltammetry (CV). Chlorophyll, heptadecanoic acid and 7.5 or 8.5 pH values were applied when nanostructured TiO2 electrode was dipped in the dye solution. Best efficiency conversion values were obtained when using fatty acids as coadsorbents, reaching a conversion efficiency of 0.04 % for open cells.
eu_rights_str_mv openAccess
format article
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identifier_str_mv Enciso, M, Decoppet, J, Moehl, T, y otros. "Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation". International Journal of Electrochemical Science. [en línea] 2016, 11 (5), pp. 3604-3614. 11 h. doi: 10.20964/110443
1452-3981
10.20964/110443
instacron_str Universidad de la República
institution Universidad de la República
instname_str Universidad de la República
language eng
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publishDate 2016
reponame_str COLIBRI
repository.mail.fl_str_mv mabel.seroubian@seciu.edu.uy
repository.name.fl_str_mv COLIBRI - Universidad de la República
repository_id_str 4771
rights_invalid_str_mv Licencia Creative Commons Atribución (CC - By 4.0)
spelling Enciso María Paula, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Química BiológicaDecoppet Jean-David, Ecole Polytechnique Federale de LausanneMoehl Thomas, Ecole Polytechnique Federale de LausanneGrätzel Michael, Ecole Polytechnique Federale de LausanneWörner Michael, Karlsruher Institut für TechnologieCerdá María Fernanda, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Química Biológica2021-01-11T15:57:02Z2021-01-11T15:57:02Z2016Enciso, M, Decoppet, J, Moehl, T, y otros. "Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation". International Journal of Electrochemical Science. [en línea] 2016, 11 (5), pp. 3604-3614. 11 h. doi: 10.20964/1104431452-3981https://hdl.handle.net/20.500.12008/2630710.20964/110443The influence of some coadsorbents and different pH values on the efficiency of DSS cells assembled with phycocyanin was evaluated using quartz crystal microbalance (QCM) and electrochemical techniques as impedance spectroscopy (EIS) and cyclic voltammetry (CV). Chlorophyll, heptadecanoic acid and 7.5 or 8.5 pH values were applied when nanostructured TiO2 electrode was dipped in the dye solution. Best efficiency conversion values were obtained when using fatty acids as coadsorbents, reaching a conversion efficiency of 0.04 % for open cells.Submitted by Parodi Mónica (mparodi@fcien.edu.uy) on 2021-01-07T18:51:25Z No. of bitstreams: 2 license_rdf: 19875 bytes, checksum: 9fdbed07f52437945402c4e70fa4773e (MD5) 1020964110443.pdf: 787293 bytes, checksum: f8c32fb396f065ba4466be9d01f8df2e (MD5)Approved for entry into archive by Faget Cecilia (lfaget@fcien.edu.uy) on 2021-01-11T15:27:08Z (GMT) No. of bitstreams: 2 license_rdf: 19875 bytes, checksum: 9fdbed07f52437945402c4e70fa4773e (MD5) 1020964110443.pdf: 787293 bytes, checksum: f8c32fb396f065ba4466be9d01f8df2e (MD5)Made available in DSpace by Luna Fabiana (fabiana.luna@fic.edu.uy) on 2021-01-11T15:57:02Z (GMT). No. of bitstreams: 2 license_rdf: 19875 bytes, checksum: 9fdbed07f52437945402c4e70fa4773e (MD5) 1020964110443.pdf: 787293 bytes, checksum: f8c32fb396f065ba4466be9d01f8df2e (MD5) Previous issue date: 201611 h.application/pdfen_USengElectrochemical Science GroupInternational Journal of Electrochemical Science, 2016, 11 (5), pp. 3604-3614.Las obras depositadas en el Repositorio se rigen por la Ordenanza de los Derechos de la Propiedad Intelectual de la Universidad de la República.(Res. Nº 91 de C.D.C. de 8/III/1994 – D.O. 7/IV/1994) y por la Ordenanza del Repositorio Abierto de la Universidad de la República (Res. Nº 16 de C.D.C. de 07/10/2014)info:eu-repo/semantics/openAccessLicencia Creative Commons Atribución (CC - By 4.0)CoadsorbentsDSSCEISPhycocyaninQCMInfluence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluationArtículoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionreponame:COLIBRIinstname:Universidad de la Repúblicainstacron:Universidad de la RepúblicaEnciso, María PaulaDecoppet, Jean-DavidMoehl, ThomasGrätzel, MichaelWörner, MichaelCerdá, María FernandaLICENSElicense.txtlicense.txttext/plain; charset=utf-84267http://localhost:8080/xmlui/bitstream/20.500.12008/26307/5/license.txt6429389a7df7277b72b7924fdc7d47a9MD55CC-LICENSElicense_urllicense_urltext/plain; charset=utf-844http://localhost:8080/xmlui/bitstream/20.500.12008/26307/2/license_urla0ebbeafb9d2ec7cbb19d7137ebc392cMD52license_textlicense_texttext/html; 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- Universidad de la Repúblicafalse
spellingShingle Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
Enciso, María Paula
Coadsorbents
DSSC
EIS
Phycocyanin
QCM
status_str publishedVersion
title Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
title_full Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
title_fullStr Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
title_full_unstemmed Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
title_short Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
title_sort Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation
topic Coadsorbents
DSSC
EIS
Phycocyanin
QCM
url https://hdl.handle.net/20.500.12008/26307